Possibilities for the identification of related propellant combinations
during the launch of rockets by photos

(with special reference to the Iranian rockets)

Norbert Brügge, Germany

Update: 13.02.2012

TG-02 / AK-20 (HNO3 + 20% N2O4)
The fuel TG-02 (= German Tonka-250) is hydrocarbons, that based on petroleum (50% Triethylamine + 50% Xylidene). The oxidizer AK-20 is a mix of 80% IRFNA (HNO3) and 20% NTO (N2O4). Nitrogen Tetroxide (N2O4) has a characteristic reddish-brown colour in both liquid and gaseous phases.  IRFNA (HNO3) is a clear to yellow liquid which is red fuming on exposure to air.
During the lift-off is a reddish cloud visible, which is caused by the oxidizer IRFNA (inhabitid red-fuming nitric acid). Furthermore, during the ascent of the rocket is permanent visible a short brown plume at the nozzle. This phenomenon is also visible at other missiles, if IRNA or AK is used as oxidizer.
The Iraqi Al-Abid has used AZ-11 (89% TG-02 +11% UDMH) as fuel. An analysis of the cloud is not possible because the images are unclear.



 



 



 
     
Prithvi Al-Samoud  Al-Abbas/Al-Abid      

TM-185 / AK-27 (HNO3 + 27% N2O4)
TM-185 is a combination of 56% Polymer-destillates with 40% Light Oil Pyrolyse and 4% Trikresol. Der oxidizer AK-27 include 73% IRFNA (HNO3) and 27% NTO (N2O4).
This combination of propellant was only used for the Soviet  R-12 and R-17 (Scud-B) missiles. During the lift-off is to see the same phenomenon as before (AK-plume). The Iranian Scud-B variants (Shahab-1, Shahab-2 and Qiam-1) fit into this scheme. The typically brown plume at the nozzle is AK-oxidizer, and not soot from hydrocarbons as it is suspected.
On the R-12 is the plume not more visible due higher outflow-velocities at all four nozzles or better combustion properties.



 


 


 


 


 
 

R-12

R-17/Scud-B  Shahab-1 Shahab-2 Qiam-1  

Turpentine / IRFNA (HNO3)
Here, the red-brown plume of IRFNA at the output of the nozzle is very intense. The cause is the use of 100% of IRFNA oxidizer.



 



 



 

   
French Veronique French Vesta

Saphir/Emeraude

Diamant-A

   

UDMH / AK-27 (HNO3 + 27% N2O4)
Even when a combination with UDMH fuel is used, is at the exit of the nozzle again visible the brown plume of AK-oxidizer.  UDMH is a clear, hygroscopic liquid which yellows on exposure to air. The cloud on the ground is varied colored by reddish-brown, yellow, brown and white.
The Iranian Shahab-3 and Ghadr-I fit into this scheme, just as the North Korean Unha-2. The existence of a R-17M/Hwasong-6 with UDMH as fuel is unconfirmed. On the R-14 and DF-3 is the plume not more visible due higher outflow-velocities in all four nozzles or better combustion properties.
An evaluation of the Safir-Omid is due the launch at night not possible.



 


 


 

 
 


 
 

R-14

 R-14/Kosmos-3  R-16

DF-3

 R-17M/Hwasong-6  


 



 



 



 


 
 
R-18/Ghauri

 R-18/Shahab-3

 Shahab-3M/Ghadr-I

 Safir-Omid

Unha-2  
     

 


 


 
 

 

  R-21 SLBM  R-27 SLBM  R-26

UDMH / N2O4
When using the combination UDMH/N2O4 is missing the red-brown plume at the nozzle clear. The cloud is brown to whitish colored. Initially may appear intensely red-brown fume or leaking liquids of the same color. It is unburned N2O4 (see UR-500, R-36, CZ, Diamant).
The Iranian Kavoshgar-1 and Safir-Rasad fit into this scheme. A permanent brown AK-plume is not present at the nozzle.



 


 

 
 

 
 


 



 

 Ariane-1  Amethyste/Diamant-B Chang Zheng (CZ) Safir-Rasad/Navid  Kavoshgar-1

UR-500/Proton



 



 



 



 



 



 

UR-200 UR-100 UR-100N/Strela UR-100NU/Rockot

 MR-UR-100

R-36/Tsiklon


 


 


 


 
   
R-36M R-36MU R-36M2/Dnepr R-29R (M)/Volna (Shtil)    

Aerozin50 / N2O4
The fuel Aerozin50 include 50% UDMH und 50% Hydrazine Hydrate. The cloud is therefore predominantly light brown to whitish colored. During the lift-off again occurring red-brown fumes, are unburned N2O4 oxidizer.



 

         

U.S. Titan

         

UH25 / N2O4
The fuel UH-25 include 75% UDMH and 25% Hydrazine Hydrate. The cloud is light brown to whitish colored. At the beginning may appear reddish-brown smoke from unburned N2O4 oxidizer.



 

         
Ariane-4